142560-84-7

Basic information

• Product Name: (3aR,4S,7R,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene
• Synonyms: (3aR,4S,7R,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene
• CAS NO: 142560-84-7
• Molecular Weight: 345.463
• Mol File: 142560-84-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3aR,4S,7R,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,4S,7R,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene(142560-84-7)
• EPA Substance Registry System: (3aR,4S,7R,7aS)-3a-Nitro-7a-((S)-(S)-2-phenyl-propane-1-sulfinyl)-2,3,3a,4,7,7a-hexahydro-1H-4,7-methano-indene(142560-84-7)

Safety Data

• Hazardous Substances Data: 142560-84-7(Hazardous Substances Data)

Upstream product

• 129396-35-6 -1-(2-phenylpropylsulfinyl)-2-nitrocyclopentene 
• 542-92-7 cyclopenta-1,3-diene 

Relevant articles and documents

Diastereoselective Diels-Alder Cycloadditions with Chiral 1-(Alkylsulfinyl)-2-nitroalkenes

Several chiral 2-nitro-1-sulfinylalkenes were prepared and examined for their utility as dienophiles for asymmetric cycloaddition.Trisubstituted dienophiles 3-6 undergo diastereoselective cycloaddition with cyclopentadiene in the presence of Lewis acids.Even the tetrasubstituted chiral sulfinyl dienophiles 1 and 2 could be coerced into undergoing cycloaddition to afford the cycloadducts in high yield without concomitant elimination if the reaction was conducted under high pressure.Generally, the Z-sulfinyl dienophiles 1-4 showed higher diastereo- and endo/exo-selectivity than the E-dienophiles 5 and 6.