142592-74-3

Upstream product

• 142592-73-2 (S)-6-(benzyloxy)-1,4-hexanediol 
• 77-76-9 2,2-dimethoxy-propane 
• 91285-62-0 (S)-1-(benzyloxy)-3-hydroxyhex-5-ene 

Downstream Products

• 142592-60-7 <2S(S),3R,6S,8S>-N-<6-hydroxy-2-(methoxycarbonyl)-3-<<2-(trimethylsilyl)ethoxy>methoxy>phenyl>-2-<1-<<1-<<2-(trimethylsilyl)ethoxy>methoxy>-2-pyrrolidyl>carbonyl>ethyl>-1,7-dioxaspiro<5.5>undecane-8-acetamide 
• 142592-58-3 <2S(2S,3R,6S,8S)>-2-<3-methyl-8-<2-(benzyloxy)ethyl>-1,7-dioxaspiro<5.5>undecan-2-yl>-1-<1-<<2-(trimethylsilyl)ethoxy>methoxy>-2-pyrrolidyl>-1-propanone 
• 142592-76-5 (βR,2S,3R,6S,8S)-2-<α-(tert-butyldiphenylsilyloxy)ethyl>-8-<2-(benzyloxy)ethyl>-β,3-dimethyl-1,7-dioxaspiro<5.5>undecane 
• 99623-84-4 Routiennocin 
• 144604-71-7 (βR,2S,3R,6S,8S)-2-[α-(tert-butyldiphenylsilyloxy)ethyl]-β,3-dimethyl-1,7-dioxaspiro[5.5]undecane-8-ethanol 
• 142592-57-2 (αR,2S,3R,6S,8S)-8-<2-(benzyloxy)ethyl>-α,3-dimethyl-1,7-dioxaspiro<5.5>undecane-2-ethanal 
• 142592-56-1 (βR,2S,3R,6S,8S)-8-<2-(benzyloxy)ethyl>-β,3-dimethyl-1,7-dioxaspiro<5.5>undecane-2-ethanol 

Relevant academic research and scientific papers

Total synthesis of the ionophore antibiotic CP-61,405 (routiennocin)

The total synthesis of the spiroketal ionophore antibiotic routiennocin 1 (CP-61,405) employing π-allyltricarbonyl iron lactone complexes is described. These complexes were used as precursors for the preparation of substituted 2-phenylsulphonyl pyrans whi