142623-70-9

Basic information

• Product Name: 4-(1H,1H,2H,2H-PERFLUORDECYLTHIO)-PHENOL
• Synonyms: 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYLTHIO)PHENOL;4-(1H,1H,2H,2H-PERFLUORODECYL-1-THIO)-PHENOL;4-(1H,1H,2H,2H-PERFLUORDECYLTHIO)-PHENOL;FluoMarTM, 4-(1H,1H,2H,2H-Perfluordecylthio)-phenol;FluoMar
• CAS NO: 142623-70-9
• Molecular Formula: C₁₆H₉F₁₇OS
• Molecular Weight: 572.28
• Mol File: 142623-70-9.mol
• Article Data: 5

Chemical Properties

• Melting Point: 90-95 °C
• Boiling Point: 346.1°C at 760 mmHg
• Flash Point: 163.1°C
• Appearance: /
• Density: 1.62g/cm³
• Vapor Pressure: 2.94E-05mmHg at 25°C
• Refractive Index: 1.395
• CAS DataBase Reference: 4-(1H,1H,2H,2H-PERFLUORDECYLTHIO)-PHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1H,1H,2H,2H-PERFLUORDECYLTHIO)-PHENOL(142623-70-9)
• EPA Substance Registry System: 4-(1H,1H,2H,2H-PERFLUORDECYLTHIO)-PHENOL(142623-70-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37
• WGK Germany: 3
• F: 10-23
• Hazardous Substances Data: 142623-70-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H9F17OS/c17-9(18,5-6-35-8-3-1-7(34)2-4-8)10(19,20)11(21,22)12(23,24)13(25,26)14(27,28)15(29,30)16(31,32)33/h1-4,34H,5-6H2

Upstream product

• 2043-53-0 2-(n-perfluorooctyl)ethyl iodide 
• 637-89-8 4-sulfanylphenol 

Downstream Products

• 514221-83-1 1H-indole-5-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 
• 944403-00-3 C₂₉H₃₅F₁₇OS 
• 514221-89-7 1-(4-methoxy-benzoyl)-piperidine-4-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 
• 514221-87-5 1-(4-chloro-benzoyl)-piperidine-4-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 
• 514221-88-6 1-benzoyl-piperidine-4-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 
• 514221-86-4 piperidine-4-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 
• 514221-85-3 piperidine-1,4-dicarboxylic acid 1-tert-butyl ester 4-[4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl] ester 
• 514221-84-2 7-methoxy-benzofuran-2-carboxylic acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-decylsulfanyl)-phenyl ester 

Relevant articles and documents

Gelation properties of aprotic low-molecular-mass organic gelators based on a Gemini 4-[2-(Perfluoroalkyl)ethylsulfanyl] phenoxy derivative unit

Gelation properties of aprotic low-molecular-mass organic gelators (LMOGs) based on a gemini 4-[2-(perfluoroalkyl)ethylsulfanyl]phenoxy derivative unit are described. These LMOGs without hydrogen-bonding functional groups produced physical gels in several organic solvents such as ethanol, 1-octanol, acetonitrile, DMF, DMSO, propylene carbonate, and γ-butyrolactone at low concentration below 1 wt %. From the results of microscope observation and nuclear magnetic resonance spectroscopy, these aprotic LMOG molecules were aggregated into tape-shaped molecular nanofibers, and formed three-dimensional networks. In addition, the self-diffusion coefficient of the solvent molecules in these networks was similar to that of neat, although these solvent molecules have non-fluidity by gelation.

AROMATIC COMPOUND GELATINIZING AGENT HAVING PERFLUOROALKYL GROUP

Aromatic compounds having a perfluoroalkyl group and a gelling agent for gelling an organic liquid which is composed of any one of them. This gelling agent can gel many kinds of organic liquids by adding a small amount thereof.

FluoMar, a fluorous version of the Marshall resin for solution-phase library synthesis

(Matrix presented) The fluorous counterpart of the Marshall resin, 4-(1H,1H,2H,2H-perfluorodecylsulfanyl)phenol (FluoMar), is prepared by S-alkylation of 4-mercaptophenol with C8F17CH 2CH2I and employed in the s