14263-81-1

Basic information

• Product Name: TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE
• Synonyms: 2,2'-BIPYRIDINE FERROUS SULFATE;TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE;tris(2,2’-bipyridine-n,n’)-iron(2++(oc-6-11)-iron(2++sulfate(1:1);0.025msolutioninwater;2,2-BIPYRIDINE IRON(II) SULFATE;2,2''-Bipyridyl ferrous sulfate;2,2-BIPYRIDINE FERROUS SULFATE 0.025M SOLN. IN WATER
• CAS NO: 14263-81-1
• Molecular Formula: C30H24FeN6O4S
• Molecular Weight: 620.46
• Mol File: 14263-81-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE(14263-81-1)
• EPA Substance Registry System: TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE(14263-81-1)

Safety Data

• Hazardous Substances Data: 14263-81-1(Hazardous Substances Data)

Usage

General Description

TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE is a complex compound consisting of ferrous sulfate and tris(2,2'-bipyridine) as a ligand. It is often used as a catalyst in various chemical reactions and in electrochemical studies due to its unique redox properties. The tris(2,2'-bipyridine) ligand is known for its ability to form stable complexes with metal ions, making it a valuable component in the development of new materials and technologies. TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE has applications in areas such as photocatalysis, photovoltaics, and sensors due to its ability to facilitate electron transfer and exhibit photochemical properties. Overall, TRIS-(2,2'-BIPYRIDINE) FERROUS SULFATE plays an important role in advancing research and innovations in the field of chemistry and materials science.

Upstream product

• 366-18-7 [2,2]bipyridinyl 
• 7439-89-6 iron(II) 

Relevant articles and documents

Photoelectron Emission Study of Iron(II) and Cobalt(II) Complexes in Aqueous Solution. Reorganization Energies

The photoelectron emission threshold energies of FeII and CoII complexes in aqueous solutions have been determined.The values could be successfully used for obtaining the reorganization energies in the one-electron oxidation reaction

Boron cluster anions [BnHn]2- (n = 10, 12) in reactions of iron(II) and iron(III) complexation with 2, 2?-bipyridyl and 1, 10-phenanthroline

Complexation of FeII and FeIII with azaheterocyclic ligands L (L = phen or bipy) were studied in the presence and in the absence of boron cluster anions [BnHn]2- (n = 10, 12). The reactions were carried out in air at room temperature in organic solvents and/or water. In all the solvents used, well known [FeL3]An (An = 2Cl- or SO42-) ferrous complexes were formed from FeII salts. Composition of ferric complexes with L ligands depends on the nature of solvent: either dinuclear oxo-iron(III) chlorides [L2ClFeIII-O-FeIIIL2Cl]Cl 2 or ferric ferrates(III) [FeIIIL2Cl 2][FeIIICl4], or [FeIIIL 2Cl2][FeIIICl4L] were isolated from FeIII salts. Introduction of the closo-borate anions to a Fe 3+(or Fe2+)/L/solv. mixture stabilizes ferrous cationic complexes [FeL3]2+ in all the solvents used: only ferrous [FeL3][BnHn] (n = 10, 12) complexes were isolated from all the reaction mixtures in the presence of boron cluster anions. Copyright

PH-tuned metal coordination and peroxidase activity of a peptide dendrimer enzyme model with a Fe(ii)bipyridine at its core

Peptide dendrimer BP1 was obtained by double thioether bond formation between 5,5′-bis(bromomethyl)-2,2′-bipyridine and two equivalents of peptide dendrimer N1 (Ac-Glu-Ser)8(Dap-Glu-Ala)4(Dap-Amb- Tyr)2Dap-Cys-Asp-NH2