1426682-75-8Relevant academic research and scientific papers
Deoxythiosugar derivatives with Furano, Pyrano, and septano motifs from L -gulono-1,4-lactone and D-glycero-D-gulo-heptono-1,4-lactone
Gunasundari, Thanikachalam,Chandrasekaran, Srinivasan
, p. 6986 - 6995 (2012)
A short synthesis of thiosugar derivatives mimicking furanose, pyranose, and septanose structures has been achieved starting from L-gulono-1,4-lactone and D-glucoheptono-1,4-lactone. Different strategies used in the synthesis are: (1) a nucleophilic displacement and Michael addition; (2) epoxide ring opening and Michael addition; (3) epoxide ring opening and nucleophilic displacement process; and (4) double nucleophilic displacement. All of these reactions used benzyltriethylammonium tetrathiomolybdate, (BnEt3N) 2MoS4 as the sulfur-transfer reagent. Copyright
