1427042-51-0

Basic information

• Product Name: 1-methoxy-3,4-bis(trimethylsilyl)benzene
• Synonyms: 1-methoxy-3,4-bis(trimethylsilyl)benzene
• CAS NO: 1427042-51-0
• Molecular Weight: 252.504
• Mol File: 1427042-51-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-methoxy-3,4-bis(trimethylsilyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-3,4-bis(trimethylsilyl)benzene(1427042-51-0)
• EPA Substance Registry System: 1-methoxy-3,4-bis(trimethylsilyl)benzene(1427042-51-0)

Safety Data

• Hazardous Substances Data: 1427042-51-0(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 36404-30-5 3,4-dichloroanisole 
• 62415-74-1 3,4-dibromoanisole 

Relevant articles and documents

Copper-Free Double Silylation of 1,2-Dibromobenzenes Using a Mg/LiCl/DMI System

The reaction of 1,2-dibromobenzenes with chlorotrimethylsilane efficiently proceeded in the presence of Mg and LiCl in DMI under mild conditions, giving 1,2-bis(trimethylsilyl)benzenes in good to high yields. The reaction of 1,2-dibromobenzenes with chlorodimethylsilane under the same conditions afforded the corresponding 1,2-bis(dimethylsilyl)benzenes in high yields. Functional group transformations of 1,2-bis(trimethylsilyl)benzene were conducted to demonstrate the synthetic utility.