1427217-99-9

Basic information

• Product Name: (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene
• Synonyms: (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene
• CAS NO: 1427217-99-9
• Molecular Weight: 503.407
• Mol File: 1427217-99-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene(1427217-99-9)
• EPA Substance Registry System: (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene(1427217-99-9)

Safety Data

• Hazardous Substances Data: 1427217-99-9(Hazardous Substances Data)

Upstream product

• 1427217-92-2 (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene 

Downstream Products

• 1569270-20-7 C₃₉H₄₂ClFeNPRh 
• 1569270-15-0 C₃₁H₃₀FeNPSe 

Relevant articles and documents

1,2-Disubstituted aryl-based ferrocenyl phosphines

Ferrocenylaryl-or ferrocenylheteroarylphosphines [Fe{1-PPh 2(spacer)-2-NMe2CH2C5H 3}(C5H5)] (spacer = 1,4-phenylene (rac-6), 1,3-phenylene (rac-7), 4,4′-biphenylene (rac-8), 2,5-thienylene (rac-9)) were prepared in a facile two-step sequence starting with Negishi cross-coupling between N,N-dimethylaminomethylferrocene and aryl halide phosphine oxides, Br-spacer-P(O)Ph2, followed by reduction with trichlorosilane. All products were characterized spectroscopically (1H, 13C, and 31P NMR, MS, FTIR), and rac-6, the corresponding phosphine oxide rac-2, and rac-9 were also characterized by X-ray crystallography. Furthermore, the redox properties of rac-2-9 were studied by cyclic voltammetry.