1427217-92-2

Basic information

• Product Name: (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene
• Synonyms: (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene
• CAS NO: 1427217-92-2
• Molecular Weight: 519.406
• Mol File: 1427217-92-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene(1427217-92-2)
• EPA Substance Registry System: (3-diphenylphosphine oxide)phenyl-2-N,N-dimethylaminomethylferrocene(1427217-92-2)

Safety Data

• Hazardous Substances Data: 1427217-92-2(Hazardous Substances Data)

Upstream product

• 10212-04-1 (3-bromophenyl)-diphenylphosphine oxide 
• 1271-86-9 N,N-dimethylaminomethylferrocene 

Downstream Products

• 1427217-99-9 (3-diphenylphosphino)phenyl-2-N,N-dimethylaminomethylferrocene 

Relevant articles and documents

Synthesis of 1,1′,2-trisubstituted aryl-based ferrocenyl phosphines as precursors for immobilized ligands

Ferrocenylaryl or ferrocenylheteroaryl phosphines bearing a carboxaldehyde group, [Fe{1-PPh2(spacer)-2-NMe2CH2C 5H3}(C5H4CHO)] (spacer = none (rac-12), 1,4-phenylene (rac-13), 1,3-phenylene (rac-14), 2,5-thienylene (rac-15)), were prepared in a facile four-step sequence starting with dibromination of N,N-dimethylaminomethylferrocene (1) followed by Negishi cross-coupling between 1,1′-dibromo-2-N,N-dimethylaminomethylferrocene (rac-2) and aryl or heteroaryl bromide phosphine oxides, Br-spacer-P(O)Ph 2 (spacer = 1,4-phenylene, 1,3-phenylene, 2,5-thienylene), reduction with trichlorosilane, and functionalization of the 1′-position of the cyclopentadienyl ring. All products were fully characterized by spectroscopy (1H, 13C, and 31P NMR, MS, IR) and for rac-3, rac-7 and rac-11 also by X-ray crystallography. Furthermore, preliminary studies on the grafting of rac-12 on silica were conducted.