1427271-38-2Relevant articles and documents
Palladium-catalyzed 1,4-difunctionalization of butadiene to form skipped polyenes
McCammant, Matthew S.,Liao, Longyan,Sigman, Matthew S.
supporting information, p. 4167 - 4170 (2013/04/24)
A palladium-catalyzed 1,4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported. Through a palladium σ → π → σ allyl isomerization, two new carbon-carbon bonds are formed with high regioselectivity and trans s