142776-09-8

Basic information

• Product Name: 1-((1R,4R)-5-Benzyl-1-methyl-2,5-diaza-bicyclo[2.2.1]hept-2-yl)-2,2,2-trifluoro-ethanone
• CAS NO: 142776-09-8
• Molecular Weight: 298.308
• Mol File: 142776-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-((1R,4R)-5-Benzyl-1-methyl-2,5-diaza-bicyclo[2.2.1]hept-2-yl)-2,2,2-trifluoro-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-((1R,4R)-5-Benzyl-1-methyl-2,5-diaza-bicyclo[2.2.1]hept-2-yl)-2,2,2-trifluoro-ethanone(142776-09-8)
• EPA Substance Registry System: 1-((1R,4R)-5-Benzyl-1-methyl-2,5-diaza-bicyclo[2.2.1]hept-2-yl)-2,2,2-trifluoro-ethanone(142776-09-8)

Safety Data

• Hazardous Substances Data: 142776-09-8(Hazardous Substances Data)

Upstream product

• 142896-78-4 C₂₇H₃₁NO₈S₃ 
• 142896-77-3 (2R,4S)-2-Methyl-1-(toluene-4-sulfonyl)-4-(toluene-4-sulfonyloxy)-pyrrolidine-2-carboxylic acid ethyl ester 
• 142776-08-7 (2S,4S)-1-(4-tolylsulfonyl)-4-<(4-tolylsulfonyl)oxy>-2-methylprolinol 
• 142824-30-4 (2R,4S)-4-Hydroxy-2-methyl-pyrrolidine-2-carboxylic acid ethyl ester; hydrochloride 
• 142776-06-5 (1R,4R)-1-methyl-2-(p-toluenesulfonyl)-5-phenylmethyl-2,5-diazabicyclo<2.2.1>heptane 
• 142796-95-0 (2S,5R,7S)-2-tert-butyl-5-methyl-4-oxo-3-oxa-1-azabicyclo<3.3.0>oct-7-yl propionate 
• 142896-75-1 (2S,4R)-4-hydroxy-2-methylproline 
• 142824-29-1 (1R,4R)-4-methyl-2-(phenylmethyl)-2,5-diazabicyclo<2.2.1>heptane dihydrobromide 
• 407-25-0 trifluoroacetic anhydride 

Downstream Products

• 142776-10-1 2,2,2-Trifluoro-1-((1R,4R)-1-methyl-2,5-diaza-bicyclo[2.2.1]hept-2-yl)-ethanone 

Relevant articles and documents

PREPARATION OF (1R,4R)-1-METHYL-2-(p-TOLUENESULFONYL)-5-PHENYLMETHYL-2,5-DIAZABICYCLOHEPTANE, INTERMEDIATE IN A SYNTHESIS OF NEW NAPHTHYRIDONES

An efficient chiral synthesis of the (1R,4R)-1-methyl-2-(p-toluenesulfonyl)-5-phenylmethyl-2,5-diazabicycloheptane (2b) was performed using trans-4-hydroxy-L-proline as starting material.This bridged piperazine was used in the preparation of new na