14283-67-1

Usage

InChI:InChI=1/C16H35OP/c1-4-7-10-11-12-13-16-18(17,14-8-5-2)15-9-6-3/h4-16H2,1-3H3

Upstream product

• 628-21-7 1,4-Diiodobutane 
• 629-27-6 1-Iodooctane 
• 3095-94-1 Octyl-P(O)Cl₂ 
• 693-04-9 butyl magnesium bromide 
• 111-66-0 oct-1-ene 
• 15754-54-8 dibutylphosphine oxide 

Relevant academic research and scientific papers

Air-induced anti-Markovnikov addition of secondary phosphine oxides and H-phosphinates to alkenes

(Chemical Equation Presented) Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism.

Peroxo-containing metal complexes having amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligands as epoxidation catalysts

PCT No. PCT/EP96/03888 Sec. 371 Date Mar. 11, 1998 Sec. 102(e) Date Mar. 11, 1998 PCT Filed Sep. 4, 1996 PCT Pub. No. WO97/10054 PCT Pub. Date Mar. 20, 1997Olefins can be epoxidized using catalysts I where M is a metal of the 4th to 7th transition group of the Periodic Table of the Elements, L1 is an amine oxide, phosphine oxide, arsine oxide, pyridine N-oxide or pyridine ligand of the formula II, III, VII or VIII, L2 is a customary auxiliary ligand or a further ligand L1 or a free coordination site, X is oxo oxygen or an imido ligand, m is 1 or 2, and n is 1, 2 or 3.

Preparation of epoxides from olefins using bis(triorganosilyl) peroxides in the presence of activators based on metallic acid derivatives

PCT No. PCT/EP97/00982 Sec. 371 Date Sep. 2, 1998 Sec. 102(e) Date Sep. 2, 1998 PCT Filed Feb. 28, 1997 PCT Pub. No. WO97/32867 PCT Pub. Date Sep. 12, 1997Epoxides are prepared from olefins using bis(triorganosilyl) peroxides in the presence of activators based on metalic acid derivatives of the formula where M is a metal of transition groups IV to VII, in particular molybdenum, tungsten or rhenium L is an uncharged ligand selected from the group consisting of amine oxides, phosphine oxides, arsine oxides, phosphoric triamides, formamides and pyridine N-oxides X is an inorganic ligand x is from 1 to 5 y is 0, 1 or 2, Z is 1 or 2 and n is 1 or 2.