14284-94-7

Usage

Uses

Used in Advanced Material Production:
Scandium (III) 2,4-pentanedionate is used as a precursor in the production of scandium-containing materials such as ceramics, catalysts, and specialty alloys. Its involvement in these processes is crucial for enhancing the properties of these materials, making them suitable for high-performance applications.
Used in Organic Chemistry:
In the realm of organic chemistry, scandium acetylacetonate serves as a Lewis acid catalyst. It is utilized to accelerate chemical reactions by accepting electron pairs, thereby increasing the reaction rates and improving the efficiency of various organic synthesis processes.
Used in Electronic and Optical Applications:
Scandium (III) 2,4-pentanedionate is employed in the development of novel materials for electronic and optical applications. Its unique properties contribute to the creation of materials with improved performance characteristics, such as enhanced conductivity, luminescence, or other optical properties, which are essential for advancing technologies in these fields.
Used in Energy Storage and Conversion:
SCANDIUM (III) 2,4-PENTANEDIONATE also plays a significant role in the advancement of energy storage and conversion technologies. Its application in these areas is instrumental in the development of more efficient and durable energy systems, which are critical for addressing the growing global energy demands and promoting sustainable energy solutions.

InChI:InChI=1/3C5H8O2.H2O.Sc/c3*1-4(6)3-5(2)7;;/h3*3,6H,1-2H3;1H2;/q;;;;+3/p-3/b3*4-3-;;

Upstream product

• 10361-84-9 scandium(III) chloride 
• 123-54-6 acetylacetone 
• 1118-67-8 sodium (Z)-4-oxopent-2-en-2-olate 

Downstream Products

• 473546-42-8 (((CH₃)2N)2C₆H₃CH₂C(COCH₃)2)(CH₃COCHCOCH₃)2Sc 
• 473546-28-0 (((CH₃)2N)2C₆H₃CH₂C(COCH₃)2)3Sc 

Relevant academic research and scientific papers

A convenient synthesis of C5(CD3)5H. Synthesis and characterisation of Fe{η5-C5(CD 3)5}2

The large scale synthesis of deuterio(pentamethylcyclopentadiene), C 5(CD3)5H ([2H30] Cp*H), and subsequent synthesis of [2H30][Fe(η- Cp*)2] is described, together with i.r., Ramah, and solid state 2H n.m.r. spectroscopic characterisation.

Synthesis and characterization of mono-(pentamethylcyclopentadienyl)alkoxyscandium alkyl derivatives, (η5-C5Me5)(OR)ScR'

Strategies for the syntheses of the title compounds are described.Cp*Sc(acac)2 (Cp* = (η5-C5Me5); acac = acetylacetonate) is prepared by treatment of Sc(acac)3 with Cp*MgClTHF.Oligomeric *ScCl2>

Sublimation kinetics of scandium β-diketonates

The volatile scandium-β-diketonates are synthesised using acetylacetone (acac) and tetramethylheptanedione (tmhd) as coordinative ligands for CVD application. The X-ray powder patterns are indexed and analysed and found to be orthorhombic and monoclinic p

Photoinduced energy- and electron-transfer processes within dynamic self-assembled donor-acceptor arrays

The synthesis and the photophysical properties of a series of noncovalently assembled donor-acceptor systems, dyads, is reported. The presented approach uses an "innocent" coordination compound, a scandium(III) acetyl acetonate derivative, as core and promotor of the dyad formation. Intercomponent photoinduced energy transfer or electron transfer within the dynamic assembly, which yields to a statistical library of donor-acceptor systems, is reported. The assemblies for energy-transfer processes are constituted by an energy donor, Ru(bpy)32+-based component (bpy = 2,2′-bipyridine), and by an energy-acceptor moiety, anthracene-based unit, both substituted with a chelating ligand, acetyl acetone, that via coordination with a scandium ion will ensure the formation of the dyad. If N,N,N′N′-tetramethyl-2,5-diaminobenzyl-substituted acetyl acetonate ligands are used in the place of 9-acyl-anthracene, intramolecular photoinduced electron transfer from the amino derivative (electron donor) to the Ru(bpy)32+-unit was detected upon self-assembly, mediated by the scandium complex. The photophysical processes can be studied on the lifetime of the kinetically labile complexes.

Rate and mechanism of ligand exchange of tris(acetylacetonato)scandium(III) in acetonitrile

Tris(acetylaceotnato)scandium(III) undergoes ligand exchange with the enolate form of acetylacetone in CD3CN at 30-74°C. The observed first-order rate constant, obtained by the 1H NMR method, is expressed by k0 = k1′[enol] + k2′ at [complex] ? 0.05 M, [Hacac] = 0.19 - 0.58 M, and [H2O] = 0.026-0.26 M; k1′ = 52 ± 3 M-1' s-1 and k2′ = 1.5 ± 0.9 s-1 at 56°C. No water catalysis was observed. The k2′ term is minor in the concentration region. The ΔH? and ΔS? values for k1′ are 36 ± 5 kJ mol-1 and -105 ± 16 J K-1 mol-1, respectively. The deuterium isotope effect k1′(H)/k1′(D) was significant (ca. 5). The Ia mechanism is assigned to the rate-determining formation of an intermediate containing a one-ended acac- and a unidentate Hacac in the enol form.