14285-56-4

Basic information

• Product Name: IRON(III) PHTHALOCYANINE CHLORIDE
• Synonyms: PHTHALOCYANINE IRON(III) MONOCHLORIDE SALT;CHLORO(PHTHALOCYANINATO)IRON(III);IRON(III) PHTHALOCYANINE CHLORIDE;chloro[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]iron;Chloro(phthalocyaninato)iron(Ⅲ);iron(II) phthalocyanine chloride;[FeCl(C32H16N8)];Iron(III) phthalocyanine chloride Dye content ~95 %
• CAS NO: 14285-56-4
• Molecular Formula: C₃₂H₁₆ClFeN₈
• Molecular Weight: 603.82
• EINECS: 238-199-3
• Mol File: 14285-56-4.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• BRN: 1200456
• CAS DataBase Reference: IRON(III) PHTHALOCYANINE CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: IRON(III) PHTHALOCYANINE CHLORIDE(14285-56-4)
• EPA Substance Registry System: IRON(III) PHTHALOCYANINE CHLORIDE(14285-56-4)

Safety Data

• Safety Statements: 22-24/25
• WGK Germany: 3
• Hazardous Substances Data: 14285-56-4(Hazardous Substances Data)

Usage

Uses

Iron catalyst for highly stereoselective C-H Amination reactions

InChI:InChI=1/C32H18N8.ClH.Fe/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;;/h1-16H,(H2,33,34,35,36,37,38,39,40);1H;/q;;+2/p-1

Upstream product

• 7705-08-0 iron(III) chloride 
• 91-15-6 phthalonitrile 
• 132-16-1 iron(II) phthalocyanine 
• 90-13-1 1-Chloronaphthalene 

Downstream Products

• 132-16-1 phthalocyaninatoiron(II) 
• 75249-87-5 μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV)) 
• 1354946-59-0 [FeCl(phthalocyanine)(2,3,5,6-tetrachloro-1,4-benzoquinone)] 
• 86086-81-9 bis-(triphenylphosphine)iminium-bis-methoxophthalocyaninatoferrate(III) 
• 86086-83-1 bis-(triphenylphosphine)iminium-bis-t-butoxophthalocyaninatoferrate(III) 
• 86086-87-5 bis-(triphenylphosphine)iminium-bis-i-propoxophthalocyaninatoferrate(III) 
• 86086-85-3 bis-(triphenylphosphine)iminium-bis-ethoxophthalocyaninatoferrate(III) 
• 102588-66-9 bis(triphenylphosphine)nitrogen diphenoxo(phthalocyaninato)ferrate(III) 
• 23388-23-0 (Fe(CH₃C₆H₄SO₃)(C₃₂H₁₆N₈)) 

Relevant articles and documents

X-ray photoelectron spectroscopy of phthalocyanine compounds

X-ray photoelectron spectra arising from carbon 1s, nitrogen 1s, and iron 2p and 3s levels of metal-free phthalocyanine (H2Pc), iron (II) phthalocyanine , and several derivatives of ironaphthalocyanine (FePcL), where L = Cl, NO and FePcL2, whe

Oxochromium compounds. 1. Synthesis and properties of μ-oxo chromium-iron porphyrin and phthalocyanine compounds

The reaction between CrIVO(P) and FeII(P′) leads to the formation of μ-oxo heterobinuclear complexes (P)CrOFe(P′) where P and P′ represent dianions of porphyrins that may be the same or different. [Abbreviations for the dianions of 5,10,15,20-tetraarylporphyrins: TPP, tetraphenylporphyrin; TTP, tetra-p-tolylporphyrin; TMP, tetrakis(p-methoxyphenyl)porphyrin; TFP, tetrakis(p-fluorophenyl)porphyrin; TCP, tetrakis(p-chlorophenyl)porphyrin; TXP, tetra-3,5-xylylporphyrin; OEP, the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin; Pc, the dianion of the phthalocyanine molecule.] The complexes react with heterocyclic Lewis bases, and these coordinate to Cr only. The visible, infrared, 1H NMR, and Mo?ssbauer spectra are reported for the compounds. The variation of magnetic susceptibility with temperature down to 4.2 K is interpreted in terms of strong antiferromagnetic coupling between Cr(III) (S = 3/2) and Fe(III) (S = 5/2) centers with J values in the range -130 to -150 cm-1. Zero field splitting effects are important at low temperatures. The reaction of CrO(TPP) with FeII(Pc) forms an analogous μ-oxo complex having porphyrin and phthalocyanine groups attached to Cr(III) and Fe(III), respectively.