IRON(III) PHTHALOCYANINE CHLORIDE

Base Information

• Chemical Name: IRON(III) PHTHALOCYANINE CHLORIDE
• CAS No.: 14285-56-4
• Molecular Formula: C32H16ClFeN8
• Molecular Weight: 603.833
• Mol file: 14285-56-4.mol

Synonyms:Iron,chloro[29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-5-12)-;Iron, chloro[phthalocyaninato(2-)]-(7CI,8CI);Chloro(phthalocyaninato)iron;Chloro[phthalocyaninato(2-)]iron;Chloroferric phthalocyanine;Chloroironphthalocyanine;Iron phthalocyanine chloride;Iron(III) phthalocyanine chloride;KJB 005;

Chemical Property of IRON(III) PHTHALOCYANINE CHLORIDE

Chemical Property:

• PSA: 84.02000
• LogP: 2.15140

Purity/Quality:

98%,99%, ^*data from raw suppliers

Iron(III) phthalocyanine chloride Dye content ~95 % ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Iron catalyst for highly stereoselective C-H Amination reactions

Technology Process of IRON(III) PHTHALOCYANINE CHLORIDE

There total 8 articles about IRON(III) PHTHALOCYANINE CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(II) phthalocyanine (132-16-1) → iron(III)phthalocyanine chloride (14285-56-4)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; refluxing of Fe-compd. in concd. HCl (20 h, according toP. A. Barret etal., J. Chem. Soc. 1157 (1938));

DOI:10.1063/1.440166

Reference yield:

iron(II) phthalocyanine (132-16-1) + 1-Chloronaphthalene (90-13-1) → iron(III)phthalocyanine chloride (14285-56-4)

Guidance literature:

With oxygen; In neat (no solvent); suspn. of Fe-complex in 1-chloronaphthalene in the presence of O2; not isolated, identified by UV-spect.;

DOI:10.1016/S0020-1693(00)86027-2

Reference yield:

Fe(C8H4N2)4CH2CH2N(C6H5)CH3*0.25C4H8O → iron(III)phthalocyanine chloride (14285-56-4)

Guidance literature:

With acetyl chloride; In tetrahydrofuran; byproducts: CH2CH2, MeC(O)NPhMe; (Ar), Fe-complex dissolved in THF, acetyl chloride added, methanol/pyridine added at -10°C; chromd. (Chromaton-N-Super), filtered, IR;

upstream raw materials:

iron(II) phthalocyanine

1-Chloronaphthalene

iron(III) chloride

phthalonitrile

Downstream raw materials:

(Fe(CH₃C₆H₄SO₃)(C₃₂H₁₆N₈))

bis(triphenylphosphine)nitrogen diphenoxo(phthalocyaninato)ferrate(III)

phthalocyaninatoiron(II)

μ-carbido-bis(tetraphenylporphyrinato(2-)iron(IV))

Refernces

• 1、 Collamati, I.. "". . p. 61 - 66. Retrieved 1986.
• 2、 Kalz, W.,Homborg, H.. "Iron(III)phthalocyanines: Preparation and Spectroscopic Characterisation of (-) (R = H, CH3, C2H5, (CH3)2CH, (CH3)3C), FePc(-2))2O and FeXPc(-2) (X = F, Cl, Br, I)". . p. 470 - 484. Retrieved 2007/10/02.