1428770-72-2

Basic information

• Product Name: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane
• Synonyms: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane
• CAS NO: 1428770-72-2
• Molecular Weight: 1032.11
• Mol File: 1428770-72-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane(1428770-72-2)
• EPA Substance Registry System: p-chlorophenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane(1428770-72-2)

Safety Data

• Hazardous Substances Data: 1428770-72-2(Hazardous Substances Data)

Upstream product

• 1428770-71-1 tri(4-iodophenyl)(4-chlorophenyl)silane 
• 495402-49-8 2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 1428770-74-4 p-(4-azobenzene)phenyl tri(3′-tert-butyldimethylsilyloxymethyl[4,1′]biphenyl)silane 

Relevant articles and documents

Synthesis of azobenzene substituted tripod-shaped bi(p-phenylene)s. Adsorption on gold and CdS quantum-dots surfaces

We report here the synthesis of several tripod-shaped oligo(p-phenylene)s with legs composed of two phenylene units. Each leg is end-capped with a thioacetate group for adhesion to metallic surfaces. An azobenzene chromophore group is present on the functional arm of the tripod. The key step in the synthesis is the Pd-catalyzed Suzuki cross-coupling reaction of the silicon derivative core molecule with substituted phenyl moieties and azobenzene derivatives. Gold surfaces prepared by thermal evaporation and CdS quantum-dots surfaces were covered by the tripod-shaped molecules. Modified surfaces were characterized by atomic force microscopy (AFM), fluorescence, and Kelvin Probe analyses.