14288-05-2Relevant articles and documents
Preparation of tertiary amides from carbamoyl chlorides and organocuprates
Lemoucheux, Laurent,Seitz, Thomas,Rouden, Jacques,Lasne, Marie-Claire
, p. 3703 - 3706 (2007/10/03)
(Chemical Equation Presented) Reaction of carbamoyl chlorides with cyano-Gilman cuprates affords tertiary amides in good to excellent yields. The reaction is general due to the possibility of using reagents made either from organolithium or from Grignard compounds. The characterization of the main side products allowed for the suggestion of a possible mechanism.
Cobalt-catalyzed aminocarbonylation of geminal dihaloalkanes. Formation of 2-aminoamide and malonamide derivatives
Miyashita,Kawashima,Kaji,Nomura,Nohira
, p. 781 - 784 (2007/10/02)
Co2(CO)8 catalyzed aminocarbonylation of geminal dihaloalkanes R2CX2 (R = H, CH3; X = Br, Cl) with NHEt2 affording R2C(NEt2)CONEt2 selectively in n-C6H14 using NEt3, while the yield of R2C(CONEt2)2 fairly increased in THF or benzene in aid of K2CO3.
DURCH NICKEL(II)-SALZE INDUZIERTE CARBAMOYLIERUNG VON ALKINEN
Fananas, F. J.,Hoberg, H.
, p. 135 - 142 (2007/10/02)
Mono- and di-substituted alkynes react with CO and secondary amines such as Et2NH in the presence of NiII salts to form carbamoyl products of the types Et2NCOC(R)=C(R')CONEt2 and RCCCONEt2.Depending on the NiX2 salt (X = Cl, Br, I) employed
