1428862-17-2Relevant academic research and scientific papers
Formation of [NiIII(κ1-S2CH)(P(o- C6H3-3-SiMe3-2-S)3)]- via CS2 insertion into nickel(III) hydride containing [Ni III(H)(P(o-C6H3-3-SiMe3-2-S) 3)]-
Lai, Kuan-Ting,Ho, Wei-Chieh,Chiou, Tzung-Wen,Liaw, Wen-Feng
, p. 4151 - 4153 (2013)
Insertion of CS2 into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S) 3)] (1), freshly prepared from the reaction of [PPN][Ni(OC 6H5)P(C6H3-3-SiMe 3-2-S)3] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe2CMe2O) in tetrahydrofuran at -80 C via a metathesis reaction, readily affords [PPN] [NiIII(κ1-S2CH)(P(o-C6H 3-3-SiMe3-2-S)3)] (2) featuring a κ1-S2CH moiety.
