142889-16-5Relevant academic research and scientific papers
REACTIONS OF 1-HALO-5-HEXENES WITH ALKYLLITHIUMS. EVIDENCE FOR A PRONOUNCED HALOGEN EFFECT ON THE MECHANISM OF THE METAL-HALOGEN INTERCHANGE REACTION OF PRIMARY ALKYL HALIDES
Bailey, William F.,Patricia, Jeffrey J.,Nurmi, Timo T.
, p. 1865 - 1868 (1986)
Reaction of t-BuLi with 1-halo-5-hexenes and 1-halo-6-methyl-5-heptenes at -78 gradC has revealed that, whereas 1 deg alkyl iodides are cleanly converted to alkyllithiums in a non-radical process, the corresponding 1 deg alkyl bromides undergo interchange at least partially via a radical-mediated, SET pathway.
