Tetrahedron Letters p. 1865 - 1868 (1986)
Update date:2022-07-30
Topics:
Bailey, William F.
Patricia, Jeffrey J.
Nurmi, Timo T.
Reaction of t-BuLi with 1-halo-5-hexenes and 1-halo-6-methyl-5-heptenes at -78 gradC has revealed that, whereas 1 deg alkyl iodides are cleanly converted to alkyllithiums in a non-radical process, the corresponding 1 deg alkyl bromides undergo interchange at least partially via a radical-mediated, SET pathway.
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