142889-22-3Relevant academic research and scientific papers
Synthesis of a Cell Wall Component of Haemophilus (Actinobacillus) Pleuropneumoniae Serotype 5
Klein, P. A. M. van der,Filemon, W.,Boons, G. J. P. H.,Veeneman, G. H.,Marel, G. A. van der,Boom, J. H. van
, p. 4649 - 4658 (2007/10/02)
The disaccharide α-D-GlcNAcp-(1-5)-β-KDO-2-OCH2CH2CH2NH2 containing a spacer β-linked to KDO is prepared via iodonium ion-assisted glycosylation of a suitable KDO acceptor with ethyl 2-azido-2-deoxy-3,4-di-O-benzyl-1-thio-α/β-D-glucopyranoside.The key KDO building unit is synthesized in 7 steps starting with 2,3:5,6-di-O-isopropylidene-D-mannitol.
