1429299-18-2Relevant academic research and scientific papers
Enantioselective 1,1-arylborylation of alkenes: Merging chiral anion phase transfer with pd catalysis
Nelson, Hosea M.,Williams, Brett D.,Miró, Javier,Toste, F. Dean
, p. 3213 - 3216 (2015)
A palladium-catalyzed three-component coupling of α-olefins, aryldiazonium salts, and bis(pinacolato)diboron affords direct access to chiral benzylic boronic esters. This process is rendered highly enantioselective using an unprecedented example of cooperative chiral anion phase transfer and transition-metal catalysis.
Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalysts
Toribatake, Kenji,Zhou, Li,Tsuruta, Ayae,Nishiyama, Hisao
supporting information, p. 3551 - 3560 (2013/05/08)
Chiral rhodium[bis(oxazolinyl)phenyl] complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated esters, ketones, and amides with bis(pinacolato)diboron in the presence of sodium tert-butoxide to attain high enantioselectivity of up to 97%. The substrate scope and catalytic mechanism were discussed.
