14295-97-7

Upstream product

• 83576-30-1 2,2,6,6-tetraphenylcyclohexanone 
• 15570-45-3 1,2,3,4-tetraphenylcyclopentadiene 
• 10034-85-2 hydrogen iodide 
• 108-94-1 cyclohexanone 

Relevant academic research and scientific papers

New Strategy for Forging Contiguous Quaternary Carbon Centers via H 2 O 2 -Mediated Ring Contraction

Stereospecific construction of contiguous quaternary carbon centers constitutes a major challenge in natural product synthesis. A general protocol that enables stereospecific construction of all stereoisomers of such a moiety remains elusive. In this article, we will discuss the oxidative ring contraction of all-substituted cyclic α-formyl ketones mediated by H 2 O 2, which provides a facile access to the stereospecific construction of contiguous quaternary carbon centers.