142952-93-0Relevant academic research and scientific papers
Heck couplings of non-activated alkenes
Crisp, Geoffrey T.,Gebauer, Markus G.
, p. 12465 - 12474 (1996)
The Heck couplings of protected 2-aminobut-3-en-1-ols with cyclohexenyl triflate can be readily carried out using a 'ligand-free' palladium catalyst, potassium carbonate and tetrabutylammonium triflate.
Palladium-catalyzed heck couplings of L-vinylglycine derivatives with vinyl and aryl halides and triflates
Crisp, Geoffrey T.,Glink, Peter T.
, p. 3541 - 3556 (2007/10/02)
The coupling of aryl and vinyl halides and triflates with L-vinylglycine derivatives under the influence of a palladium catalyst is described. The coupling is regioselective and stereoselective with the absolute configuration of the α-amino acid centre be
