1430076-20-2

Upstream product

• 603-76-9 1-methylindole 
• 5153-69-5 4-fluoro-β-nitrostyrene 
• 706-08-1 trans-1-(4-fluorophenyl)-2-nitro-ethene 
• 1076-74-0 5-methoxy-2-methyl-1H-indole 

Relevant academic research and scientific papers

A robust heterogeneous Co-MOF catalyst in azide-alkyne cycloaddition and Friedel-Crafts reactions as well as hydrosilylation of alkynes

Organic reactions using metal-organic frameworks (MOFs) as catalysts are promising with regard to their environmentally friendly features and potential catalyst recyclability. A robust Co(ii)-MOF {[Co2(l-mac)(4,4-bpt)(H2O)]·3.5H2O}n (1) and its enantiomer {[Co2(d-mac)(4,4-bpt)(H2O)]·3.5H2O}n (2) (l/d-mac = basic forms of l/d-malic acid, 4,4-Hbpt = 3,5-di(pyridin-4-yl)-4H-1,2,4-triazole) have been gram-scale prepared under solvothermal conditions. Structural analysis reveals that mac manages Co(ii) ions to form 1-D chains, which are further extended via 4,4-bpt connectors into a noninterpenetrating 3D framework architecture. It was found that 1 can be as a heterogeneous catalyst for multiple organic reactions, such as azide-alkyne cycloaddition and Friedel-Crafts reactions with good isolated yields and good recycle runs (at least five times without substantial degradation). Additionally, 1 can promote hydrosilylation of alkynes under harsh conditions with moderate yield. This journal is

Rose bengal as photocatalyst: Visible light-mediated Friedel-Crafts alkylation of indoles with nitroalkenes in water

A novel and facile visible-light-mediated alkylation of indoles and nitroalkenes has been developed. In this protocol, rose bengal acts as a photosensitizer, and environmentally benign water was used as the green and efficient reaction medium. Indoles rea

Charge-enhanced thiourea catalysts as hydrogen bond donors for Friedel?Crafts Alkylations

Charge-enhanced catalysis has emerged as a powerful alternative to the mainstream use of neutral catalysis. With this in mind, we report a catalytic Friedel?Crafts alkylation method catalyzed by a charged thiourea incorporating a cationic cyclopropenium m

Catalytic and conductivity studies in two dimensional coordination polymers built with a thiazole based ligand

The employment of the commercial available organic ligand 2-mercapto-4-methyl-5-thiazoleacetic acid (H2L) in Zn and Cd chemistry yields two-dimensional (2D) coordination polymers (CPs) with pseudopolymorphic character. Thermal, catalytic and co

Quantification of Catalytic Activity for Electrostatically Enhanced Thioureas via Reaction Kinetics and UV-vis Spectroscopic Measurement

Charged thiourea derivatives containing one and two methylated or octylated pyridinium ion centers and a tetraarylborate or triflate counteranion are reported. These novel catalysts are much more active in the Friedel-Crafts reactions of trans-β-nitroalke

D-camphor-10-sulfonic acid: A water compatible organocatalyst for Friedel-Crafts reaction of indoles with electron deficient olefins

A recyclable natural product derived Bronsted acid (D-CSA) catalyzes the Friedel-Crafts addition of indole derivatives to nitroalkenes and enones in water at room temperature in good to excellent yields (71-98%).