1430117-76-2

Upstream product

• 1430117-75-1 methyl 4,4-bis((benzyloxy)methyl)-2-oxocyclopentanecarboxylate 
• 1430117-87-5 dimethyl 3,3-bis((benzyloxy)methyl)hexanedioate 
• 80595-07-9 (((cyclohex-3-ene-1,1-diylbis(methylene))bis(oxy))bis(methylene))dibenzene 
• 1430117-91-1 C₂₂H₂₆O₆ 
• 2160-94-3 4,4-bis(hydroxylmethyl)cyclohexene 
• 100-39-0 benzyl bromide 

Downstream Products

• 1430117-77-3 methyl 3,3-bis((benzyloxy)methyl)-5-oxo-2-(prop-2-yn-1-yl)cyclopentanecarboxylate 

Relevant academic research and scientific papers

Synthesis of the 10-azatricyclo[3.3.2.04,8]decane core of C 20-diterpenoid alkaloid racemulsonine via iodine(III) promoted transannular aziridination reaction

The functionalized A/E/F ring system of C20-diterpenoid alkaloid racemulsonine has been efficiently synthesized. The Key steps involved a diastereoselective Au(I)-catalyzed annulation to form cis-fused cyclopentene and a PIDA promoted transannular aziridination of primary amine followed by regio- and stereoselective ring cleavage of bridged aziridine.