143064-49-7

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 774-48-1 (diethoxymethyl)benzene 
• 100-52-7 benzaldehyde 
• 122-51-0 orthoformic acid triethyl ester 
• 64-17-5 ethanol 

Downstream Products

• 172264-96-9 <α-(Benzotriazol-1-yl)-α-ethoxypropyl>benzene 
• 304459-79-8 1-(3-Ethoxy-1-phenoxy-3-phenyl-propyl)-1H-benzotriazole 
• 202396-06-3 1-(benzotriazol-1-yl)ethyl phenyl ether 
• 107059-12-1 2-ethoxy-1,2-diphenylethanol 
• 2431-02-9 2-hydroxy-1-phenyl-2-p-tolyl-ethanone 
• 93-55-0 1-phenyl-propan-1-one 
• 1370291-56-7 potassium benzoyltrifluoroborate 
• 143064-67-9 (1R*,2R*,3S*)-1,2-diphenyl-1-ethoxy-3-methoxybutane 
• 143064-67-9 (1R*,2R*,3R*)-1,2-diphenyl-1-ethoxy-3-methoxybutane 
• 143064-56-6 (1R*,3R*)-1,3-diethoxy-1,3-diphenylpropane 
• 143064-56-6 (1R*,3S*)-1,3-diethoxy-1,3-diphenylpropane 
• 143064-57-7 (1R*,3R+)-1,3-diethoxy-1,3-diphenyl-4-nonyne 
• 143064-57-7 (1R*,3S*)-1,3-diethoxy-1,3-diphenyl-4-nonyne 
• 143064-77-1 (2S*,3R*,6R*)-3-(α-ethoxybenzyl)-2-methyltetrahydrofuran 

Relevant academic research and scientific papers

Synthesis of acyltrifluoroborates

Acylboranes are among the most elusive boron-containing organic functional groups, a fact that has impeded development of new reactions employing them as substrates. A new synthesis of acyltrifluoroborates from benzotriazole (Bt)-based N,O-acetals has bee

Benzotriazole-Mediated Conversions of Aromatic and Heteroaromatic Aldehydes to Functionalized Ketones

Aromatic and heteroaromatic aldehydes reacted with benzotriazole and triethyl orthoformate in THF to give the corresponding α-(benzotriazol-1-yl)aryl ethyl ethers 7 in good yield.The novel acyl anion precursors 7 underwent smooth lithiation at the methine group followed by trapping with alkyl halides, aldehydes, ketones, and imines to yield the expected substituted intermediates of type 9, which were hydrolyzed under mild conditions without isolation.Benzaldehyde, methyl-, chloro-, and methoxy-substituted benzaldehydes, 1-naphthalenecarboxaldehyde, 2- and 3-furaldehydes, 2- and 3-thiophenecarboxaldehydes, and 2-pyridinecarboxaldehyde were all transformed in this manner into a variety of aryl and heteroaryl ketones with alkyl (10), α-hydroxyalkyl (12 and 13), α-aminoalkyl (14) and acyl (15) substituents.

Addition of 1-(α-Alkoxybenzyl)benzotriazoles to Enol Ethers. New Routes to 1,3-Diethers

1-(α-Alkoxybenzyl)benzotriazoles undergo reversible ionization in solution to a benzotriazolyl anion (Bt-) and carboxonium cations PhCH:O+R.These cations can attack the β carbon of enol ethers to give cation adducts which add the Bt