14309-15-0Relevant articles and documents
Hybrid super electron donors - Preparation and reactivity
Garnier, Jean,Thomson, Douglas W.,Zhou, Shengze,Jolly, Phillip I.,Berlouis, Leonard E. A.,Murphy, John A.
, p. 994 - 1002 (2012)
Neutral organic electron donors, featuring pyridinylidene-imidazolylidene, pyridinylidene-benzimidazolylidene and imidazolylidene-benzimidazolylidene linkages are reported. The pyridinylidene-benzimidazolylidene and imidazolylidene-benzimidazolylidene hyb
Synthesis and vitamin D receptor affinity of 16-oxa vitamin D3 analogues
Ibe, Kouta,Yamada, Takeshi,Okamoto, Sentaro
, p. 10188 - 10200 (2019)
Two novel 16-oxa-vitamin D3 analogues were synthesized using a tandem Ti(ii)-mediated enyne cyclization/Cu-catalyzed allylation, Ru-catalyzed ring-closing metathesis reaction, and a low-valent titanium (LVT)-mediated stereoselective radical red
Promising fungicides from allelochemicals: Synthesis of umbelliferone derivatives and their structure–activity relationships
Pan, Le,Lei, Dongyu,Jin, Lu,He, Yuan,Yang, Qingqing
, (2018/11/24)
Umbelliferone was discovered to be an important allelochemical in our previous study, but the contribution of its activity and structure has not yet been revealed. In this study, a series of analogues were synthesized to determine the skeleton of umbelliferone and examine its fungicidal activity. Furthermore, targeted modifications were conducted with three plant parasitic fungi to examine the lead compounds. Among those tested, compounds 2f and 10 were found to show excellent antifungal activity with an inhibitory rate over 80% at 100 ug/mL. The study proves that umbelliferone can be a promising skeleton for fungicides discovery. In addition, the primary structure–activity relationship provides a good guidance for the discovery of novel fungicides based on natural products in the future.
Hydrodehalogenation of Haloarenes by a Sodium Hydride–Iodide Composite
Ong, Derek Yiren,Tejo, Ciputra,Xu, Kai,Hirao, Hajime,Chiba, Shunsuke
supporting information, p. 1840 - 1844 (2017/02/05)
A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.