14315-34-5Relevant academic research and scientific papers
A widely varying range of products in reactions of C6F5BrF2, C6F5IF2, and C6F5IF4 with Lewis acids of different strength
Frohn, Hermann-Josef,Bailly, Frank,Welting, Dirk,Bardin, Vadim V.
experimental part, p. 301 - 307 (2009/12/04)
The relative fluoride donor ability: C6F5BrF2 > C6F5IF2 > C6F5IF4 was outlined from reactions with Lewis acids of graduated strength in different solvents.
The first hydrogen containing (polyfluorocycloalken-1-yl)xenon(II) salts
Frohr,Bardin
, p. 562 - 564 (2007/10/03)
(2-H-Hexafluoro-1,4-cyclohexadien-1-yl)xenon(II) and (2-H-octafluorocyclohexen-1-yl)xenon(II) hexafluoroarsenates and tetrafluoroborates were obtained together with their perfluorinated analogues on reacting the corresponding (2,3,4,5-tetrarluorophenyl)xenon(II) salts with XeF2 in anhydrous HF (aHF). The fluorinated (cyclohexen-1-yl)xenon(II) cations react with bromide and iodide anions in MeCN and aHF under alkenylation of the halide anions.
FLUORINATION OF POLYFLUOROAROMATIC COMPOUNDS WITH VANADIUM PENTAFLUORIDE
Bardin, V. V.,Avramenko, A. A.,Furin, G. G.,Yakobson, G. G.,Krasilnikov, V. A.,et al.
, p. 37 - 46 (2007/10/02)
Fluorination of polyfluoro-derivatives of benzene and diphenyl with vanadium pentafluoride at -25 to -10 deg C afforded fluorinated cyclohexadienes and cyclohexenes.Octafluoronaphthalene was converted under these conditions to perfluoro-1,4-dihydronaphthalene, perfluorotetralin, perfluoro-1,4,5,8-tetrahydronaphthalene and perfluoro-1,2,3,4,5,8-hexahydronaphthalene.
