143171-99-7

Upstream product

• 864513-47-3 [RhIr(CO)3(μ-Ph2PCH2PPh2)2] 
• 333-27-7 methyl trifluoromethanesulfonate 
• 126501-61-9 [RhIr(CO)3(dppm)2] 

Downstream Products

• 143172-02-5 [RhIr(CH3)(CO)2(μ-H)(μ-Cl)(Ph2PCH2PPh2)2]OSO2CF3 
• 224620-30-8 ((CH₃)3P)RhIr(CH₃)(CO)3(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*O₃SCF₃^(1-)=[((CH₃)3P)RhIr(CH₃)(CO)3(((C₆H₅)2P)2CH₂)2]OSO₂CF₃ 
• 224620-32-0 ((CH₃)3P)RhIr(CH₃)(CO)2(((C₆H₅)2P)2CH₂)2⁽¹⁺⁾*O₃SCF₃^(1-)=[((CH₃)3P)RhIr(CH₃)(CO)2(((C₆H₅)2P)2CH₂)2]OSO₂CF₃ 
• 201230-82-2 carbon monoxide 
• 173538-72-2 [RhIr(CO)2(μ-C(CH3)=NtBu)(Ph2PCH2PPh2)2]OSO2CF3 
• 143172-06-9 {RhIr(CO)2(CH₃)(C₂H₄)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*CF₃SO₃^(1-)={RhIr(CO)2(CH₃)(C₂H₄)((C₆H₅)2PCH₂P(C₆H₅)2)2}{CF₃SO₃} 
• 143172-04-7 {RhIr(CO)3(COCH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*CF₃SO₃^(1-)={RhIr(CO)3(COCH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}{CF₃SO₃} 

Relevant academic research and scientific papers

Heterobinuclear alkyl complexes of rhodium and iridium. Migratory insertion or Ir-to-Rh migration of a methyl group in reactions with small molecules

The reaction of [RhIr(CO)3(dppm)2] (dppm = Ph2PCH2PPh2) with methyl triflate yields [RhIr(CH3)(CO)3(dppm)2][CF3SO 3] (2), having the methyl group

Binuclear alkyl complexes: Unusual ethylene adducts and facile C-H activation of a methyl group by an adjacent metal

The reactions of [MIr(CO)3(dppm)2] (M = Rh, Ir; dppm = Ph2PCH2PPh2) with methyl triflate yield [RhIr(CH3)(CO)3(dppm)2] [CF3SO3] and the unusual product of C-H activation of a methyl group [Ir2H(CO)3(μ-CH2)(dppm)2] [CF3SO3], respectively. The reactivities of these species with small molecules such as H2, CO, C2H4, and PR3 are reported.