1432-38-8

Basic information

• Product Name: (4-methoxyphenyl)(dimethyl)silane
• Synonyms: Silane, (4-methoxyphenyl)dimethyl-
• CAS NO: 1432-38-8
• Molecular Formula: C₉H₁₄OSi
• Molecular Weight: 166.2924
• Mol File: 1432-38-8.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 209.2°C at 760 mmHg
• Flash Point: 80.3°C
• Vapor Pressure: 0.297mmHg at 25°C
• CAS DataBase Reference: (4-methoxyphenyl)(dimethyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methoxyphenyl)(dimethyl)silane(1432-38-8)
• EPA Substance Registry System: (4-methoxyphenyl)(dimethyl)silane(1432-38-8)

Safety Data

• Hazardous Substances Data: 1432-38-8(Hazardous Substances Data)

Upstream product

• 2372-33-0 chlorodimethyl(4-methoxyphenyl)silane 
• 1066-35-9 dimethylmonochlorosilane 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 623-12-1 4-chloromethoxybenzene 
• 696-62-8 para-iodoanisole 
• 14774-77-7 p-methoxyphenyllithium 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 52328-41-3 [(4-Methoxy-phenyl)-dimethyl-silanyl]-acetic acid methyl ester 
• 34919-59-0 p-Methoxyphenyldimethylethylsilan 
• 622382-76-7 2-[(4-methoxyphenyl)dimethylsilylmethylene]hexanal 
• 875612-12-7 (Z)-3-methyl-2-[(dimethyl-4-methoxyphenylsilyl)methylene]-3-(p-tosylamino)butanal 
• 688-73-3 tri-n-butyl-tin hydride 
• 124862-43-7 H₃COC₆H₄Si(CH₃)2Ge(CH₃)2H 
• 22868-26-4 (p-methoxyphenyl)dimethylsilanol 
• 122571-17-9 1,3-bis(4′-methoxyphenyl)-1,1,3,3-tetramethyldisiloxane 
• 92495-54-0 4'-methoxy-2-methylbiphenyl 

Relevant articles and documents

Selective Electrochemical Hydrolysis of Hydrosilanes to Silanols via Anodically Generated Silyl Cations

The first electrochemical hydrolysis of hydrosilanes to silanols under mild and neutral reaction conditions is reported. The practical protocol employs commercially available and cheap NHPI as a hydrogen-atom transfer (HAT) mediator and operates at room temperature with high selectivity, leading to various valuable silanols in moderate to good yields. Notably, this electrochemical method exhibits a broad substrate scope and high functional-group compatibility, and it is applicable to late-stage functionalization of complex molecules. Preliminary mechanistic studies suggest that the reaction appears to proceed through a nucleophilic substitution reaction of an electrogenerated silyl cation with H2O.

Intermolecular Dehydrogenative C?H/Si?H Cross-Coupling for the Synthesis of Arylbenzyl Bis(silanes)

An iridium-catalyzed intermolecular dehydrogenative C?H/Si?H cross-coupling reaction for the synthesis of arylbenzyl bis(silanes) is developed. This hydrosilyl group steered intermolecular C?H silylation process features high chemo- and regioselectivity,

Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis

A synergistic combination of photoredox and polarity reversal catalysis enabled a hydrogen evolution cross-coupling of silanes with H2O, alcohols, phenols, and silanols, which afforded the corresponding silanols, monosilyl ethers, and disilyl ethers, respectively, in moderate to excellent yields. The dehydrogenative cross-coupling of Si-H and O-H proceeded smoothly with broad substrate scope and good functional group compatibility in the presence of only an organophotocatalyst 4-CzIPN and a thiol HAT catalyst, without the requirement of any metals, external oxidants and proton reductants, which is distinct from the previously reported photocatalytic hydrogen evolution cross-coupling reactions where a proton reduction cocatalyst such as a cobalt complex is generally required. Mechanistically, a silyl cation intermediate is generated to facilitate the cross-coupling reaction, which therefore represents an unprecedented approach for the generation of silyl cationviavisible-light photoredox catalysis.