143207-05-0Relevant articles and documents
Unusual Behaviour of Some γ- and δ-Lactones Towards Dichloromethylenation using Tris(dimethylamino)phosphine-Tetrachloromethane
Bandzouzi, Alphonse,Lakhrissi, Mohammed,Chapleur, Yves
, p. 1471 - 1474 (2007/10/02)
Lactones derived from D-glucose, D-mannose and L-ascorbic acid reacted unexpectedly with tris(dimethylamino)phosphine-tetrachloromethane to give, respectively, dichloroalkene, anomeric vinyl chloride or acyl chloride; this behaviour supports an ionic mech