143212-41-3Relevant articles and documents
Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium
Yang, Fanglong,Zhao, Gang,Ding, Yu
, p. 2839 - 2841 (2007/10/03)
Reaction of Cp2TiCl2/Mg with propargyl acetates form allenyl titanium intermediates, which undergo nucleophilic addition reactions to aldehydes or ketones to give homopropargyl alcohols in high yields. Subsequent nucleophilic additio
Preparation and reactions of allenic zirconium species from propargylic ether derivatives
Ito,Nakamura,Taguchi,Hanzawa
, p. 3769 - 3772 (2007/10/02)
The generation of allenic zirconium intermediates by treating propargylic ether derivatives with 'Cp2Zr' and their reactions with aldehydes in the presence of borontrifluoride etherate yield anti-β-acetylenic alcohols along with α-allenic alcohols.