1432447-64-7

Basic information

• Product Name: (1-(3-cyclopropylidene-1-methylcyclopentyl)vinyl)benzene
• CAS NO: 1432447-64-7
• Molecular Weight: 224.346
• Mol File: 1432447-64-7.mol

Chemical Properties

• CAS DataBase Reference: (1-(3-cyclopropylidene-1-methylcyclopentyl)vinyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1-(3-cyclopropylidene-1-methylcyclopentyl)vinyl)benzene(1432447-64-7)
• EPA Substance Registry System: (1-(3-cyclopropylidene-1-methylcyclopentyl)vinyl)benzene(1432447-64-7)

Safety Data

• Hazardous Substances Data: 1432447-64-7(Hazardous Substances Data)

Upstream product

• 1432447-63-6 3-methyl-3-(1-phenylvinyl)cyclopentanone 
• 14114-05-7 cyclopropyltriphenylphosphonium bromide 
• 98-81-7 1-bromovinylbenzene 
• 2758-18-1 3-Methyl-2-cyclopenten-1-one 

Relevant articles and documents

Gold(I)-catalyzed formation of bicyclo[4.2.0]oct-1-enes

Gold(I) catalysts effectively promote the Cope rearrangement of acyclic 1,5-dienes bearing a terminal cyclopropylidene. When this methodology is applied to cyclic substrates an unexpected transformation occurs, resulting in the formation of a tricyclic compound incorporating a bicyclo[4.2.0]oct-1-ene core, a portion of which is found in a number of natural products. Density functional theory calculations (M06 and M06-2X) reveal insight into the mechanism and thermodynamics of this unique transformation.