1433-08-5Relevant academic research and scientific papers
Syntheses of pterocarpenes and coumestans via regioselective cyclodehydration
Nayak, Maloy,Jung, Youngeun,Kim, Ikyon
, p. 8074 - 8087 (2016/09/09)
A highly efficient synthetic route to pterocarpenes and coumestans is described. BCl3-mediated dehydrative cyclization of 1,3-diaryloxyacetones under mild conditions permitted regioselective ring closure to afford 3-((2-iodoaryloxy)methyl)benzo
6-endo heck cyclization of 3-(2-iodophenoxy)methylbenzofurans: A useful approach to pterocarpenes
Fowler, Katherine J.,Ellis, Jillian L.,Morrow, Gary W.
, p. 1676 - 1682 (2013/05/21)
Mitsunobu coupling of 3-hydroxymethylbenzofurans with o-iodophenols affords 3-(2-iodophenoxy)methylbenzofurans which under go a useful 6-endo Heck cyclization under Jeffery conditions to afford pterocarpene-type heterocycles. The unsubstituted parent pterocarpene thus prepared was readily converted to coumestan via subsequent PCC oxidation. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications1 to view the free supplemental file. Copyright Taylor & Francis Group, LLC.
Smooth Conversion of 3,4-Diarylcoumarins and 3,4,5-Triaryl-2(5H)-furanones to 2H-Chromene and 2,5-Dihydrofuran Derivatives with Dimethyl Sulfide-Borane Complex
Verma, Parul,Singh, Sangeeta,Dikshit, D. K.,Ray, Suprabhat
, p. 68 - 70 (2007/10/02)
Reaction of 3,4-diarylcoumarins (3,4-diaryl-2-oxo-2H-1-benzopyrans) and 3,4,5-triaryl-2(5H)-furanones with dimethyl sulfide-borane complex affords the corresponding 2H-chromenes (2H-1-benzopyrans) and 2,5-dihydrofurans in high yields. 3,4-Diaryl-2(5H)-fur
Studies on the Constituentes of Lespedeza cyrtobotrya MIQ. I. The Structures of a New Chalcone and Two New Isoflav-3-ens
Miyase, Toshio,Ueno, Akira,Noro, Tadataka,Fukushima, Seigo
, p. 1172 - 1177 (2007/10/02)
The bark of Lespedeza cyrtobotrya MIQ. afforded a new chalcone, lespeol (I), together with xanthoangelol (II).The heartwood of Lespedeza cyrtobotrya MIQ. afforded two new isoflav-3-ens, haginin A (IIIa) and B (IVa), together with genistein, daidzein, dalbergioidin, 3,9-dihydroxypterocarp-6a-en and isoliquiritigenin.The structures were established on the basis of chemical and spectral data. Keywords---Lespedeza cyrtobotrya MIQ.; lespeol; xanthoangelol; haginin A; haginin B; 3,9-dihydroxypterocarp-6a-en; genistein; daidzein; dalbergioidin; isoliquiritigenin
