1433014-95-9

Upstream product

• 84272-19-5 (4S)-4-isopropyl-1,3-oxazolidine-2-thione 
• 2026-48-4 (S)-valinol 
• 1433014-73-3 (S)-2-diazo-1-(4-isopropyl-2-thioxooxazolidin-3-yl)ethanone 
• 100-52-7 benzaldehyde 

Downstream Products

• 1433015-02-1 (S)-4-isopropyl-3-((2S,3S)-3-phenylthiirane-2-carbonyl)oxazolidin-2-one 
• 17016-83-0 (4S)-4-isopropyl-1,3-oxazolidin-2-one 
• 1433017-41-4 S-((1R,2S)-1-chloro-3-((S)-4-isopropyl-2-oxooxazolidin-3-yl)-3-oxo-1-phenylpropan-2-yl) ethanethioate 
• 1433017-48-1 C₁₇H₂₀ClNO₄S 
• 1433017-56-1 S-((1R,2S)-1-bromo-3-((S)-4-isopropyl-2-oxooxazolidin-3-yl)-3-oxo-1-phenylpropan-2-yl) ethanethioate 
• 1433017-63-0 C₁₇H₂₀BrNO₄S 

Relevant academic research and scientific papers

N-(diazoacetyl)oxazolidin-2-thiones as sulfur-donor reagents: Asymmetric synthesis of thiiranes from aldehydes

Sulfur tyranny: Thiiranes, instead of oxiranes, can be obtained in a highly stereoselective manner through the cycloaddition reaction of N-acyl oxazolidine tethered diazo thione compounds with aldehydes catalyzed by RhII. Thus, this reaction provides versatile adducts S functionalized at both the α and β position, with concomitant generation of two contiguous stereocenters. Copyright