1433061-16-5

Basic information

• Product Name: C₁₆H₃₀O₂Si₂
• CAS NO: 1433061-16-5
• Molecular Weight: 310.584
• Mol File: 1433061-16-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₃₀O₂Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₃₀O₂Si₂(1433061-16-5)
• EPA Substance Registry System: C₁₆H₃₀O₂Si₂(1433061-16-5)

Safety Data

• Hazardous Substances Data: 1433061-16-5(Hazardous Substances Data)

Upstream product

• 15288-53-6 o-(trimethylsilyl)phenol 
• 1433060-94-6 C₁₀H₁₆O₂Si 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 444095-29-8 2-hydroxy-3-(trimethylsilyl)benzaldehyde 

Downstream Products

• 1433061-46-1 C₂₁H₃₈O₄Si₂ 
• 1433062-06-6 (2R)-ethyl 2-(2’-bromomethyl-6’-trimethylsilylphenoxyl)propanoate 
• 1433061-76-7 C₁₅H₂₄O₄Si 

Relevant articles and documents

Asymmetric induction via short-lived chiral enolates with a chiral C-O axis

A novel method has been developed for the asymmetric cyclization of alkyl aryl ethers. The reactions were assumed to proceed via short-lived chiral enolate intermediates with a chiral C-O axis to give cyclic ethers with tetrasubstituted carbon in up to 99% ee. The half-life of racemization of the chiral enolate intermediate was roughly estimated to be ～1 s at -78 C.