1433223-47-2Relevant academic research and scientific papers
Kinetic resolution of β-substituted olefinic carboxylic acids by asymmetric bromolactonization
Murai, Kenichi,Matsushita, Tomoyo,Nakamura, Akira,Hyogo, Norimichi,Nakajima, Junki,Fujioka, Hiromichi
, p. 2526 - 2529 (2013/07/19)
A strategically novel kinetic resolution of β-substituted olefinic carboxylic acids is developed by asymmetric bromolactonization using an organocatalyst, 4-tBuPh-tris 1b. The cyclization stage, which provides δ-lactone, is proposed to be operative for discrimination of each enantiomer of carboxylic acids.
