143337-13-7

Basic information

• Product Name: {(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}⁽¹⁺⁾*Cl^(1-)={(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}Cl
• CAS NO: 143337-13-7
• Molecular Weight: 917.819
• Mol File: 143337-13-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}⁽¹⁺⁾*Cl^(1-)={(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}Cl(CAS DataBase Reference)
• NIST Chemistry Reference: {(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}⁽¹⁺⁾*Cl^(1-)={(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}Cl(143337-13-7)
• EPA Substance Registry System: {(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}⁽¹⁺⁾*Cl^(1-)={(C₁₀H₆(P(C₆H₅)2))2Ru(CH₃CN)3Cl}Cl(143337-13-7)

Safety Data

• Hazardous Substances Data: 143337-13-7(Hazardous Substances Data)

Upstream product

• 126251-92-1 {RuCl(C₆H₆)((S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl)}Cl 
• 75-05-8 acetonitrile 

Relevant articles and documents

Synthesis and Characterization of Mono- and Tri-nuclear Ruthenium Complexes of 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl and Their Catalytic Activity

The structures of ruthenium(II) complexes formed in solution from Y (S)-3 (X, Y = halide and/or BF4-; binap = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; arene = benzene or p-cymene) depend on the solvent.In acetonitrile-methanol (1:1) dicationic complexes X(Y) (S)-4 (X = Y = Cl a; X = Cl, Y = BF4 b; X = Y = Br c; or X = Y = I d) are predominantly formed, while monocationic species X (S)-6 (X = Cl a, Br b or I c) were observed in acetonitrile.These mono- and di-cationic species could not be isolated pure, while (S)-5 was isolated from (S)-4a or (S)-6a upon concentration of the reaction mixture.In methanol without donor molecules such as acetonitrile, cationic trinuclear complexes Y (S)-7 (X = Y = Cl a; X = Cl, Y = BF4 b or X = Y = Br c) were exclusively formed by heating at 60 deg C or UV irradiation of a solution of (S)-3.The structure of (S)-7 was characterized by spectral data and an X-ray crystallographic analysis of (S)-7b 12121, a = 26.328(5), b = 18.140(3), c = 26.374(4), Z = 4, R'= 0.083>.The relationship between the structure of the RuII(binap) complexes and their catalytic activities for asymmetric hydrogenation of methyl 3-oxobutanoate has been investigated.