143360-75-2Relevant academic research and scientific papers
Studies towards iodine-catalyzed dehydrative-cycloisomerization of pent-4-yne-1,2-diols to di- and tri-substituted furans
Rao, H. Surya Prakash,Satish, Vijjapu,Kanniyappan, Silambarasan,Kumari, Priyanka
, p. 6047 - 6056 (2018/09/11)
An efficient and single-step iodine catalyzed and metal-free synthesis of di and tri-substituted 2-methylfuran derivatives were achieved from 1-popargyl-1,2-diols. Stereospecific synthesis of starting 1,2-diols was achieved by indium mediated Barbier type
Asymmetric hydrogenation of disubstituted furans
Wysocki, Jedrzej,Ortega, Nuria,Glorius, Frank
supporting information, p. 8751 - 8755 (2014/08/18)
An enantioselective hydrogenation of disubstituted furans has been developed by using a chiral ruthenium catalyst with N-heterocyclic carbene ligands. This reaction converts furans into valuable enantioenriched disubstituted tetrahydrofurans.
Suzuki-Miyaura cross-coupling reaction of 1,2-oxaborol-2(5H)-ols with carboxylic anhydrides: A new method to furans
Yu, Tao,Wu, Xin-Yan,Yang, Jun
supporting information, p. 4071 - 4074 (2014/07/22)
An efficient one-step method has been developed to construct furans via a Suzuki-Miyaura cross-coupling reaction of 1,2-oxaborol-2(5H)-ols with carboxylic anhydrides. In the presence of Pd(OAc)2/PCy3, the multi-substituted alkenylboron compounds could couple with anhydrides to obtain furans in moderate-to-good yields. The addition of bases promoted the coupling reaction, and the plausible reaction mechanism was proposed.
Indium-mediated allenylation of arylacyl bromides in a route for the synthesis of substituted furans
Lin, Mei-Huey,Kuo, Chung-Kai,Huang, Yen-Chih,Tsai, Yu-Ting,Tsai, Chang-Hsien,Liang, Kung-Yu,Li, Yi-Syuan,Chuang, Tsung-Hsun
, p. 5513 - 5518 (2015/03/30)
A three-step, single purification procedure has been developed for the concise synthesis of substituted furans from arylacyl bromides.
Electrosynthesis of 4-Aryl-2-Methylfurans
Barba, Fructuoso,Fuente, Jose Luis de la
, p. 3911 - 3914 (2007/10/02)
The electrochemical reduction on Hg cathode of a dropping solution of phenacyl bromides in dry acetone-LiClO4 yields 4-aryl-2-methylfurans and acetophenones.In this process the acetone plays a dual role, as solvent and reagent.
