143377-01-9Relevant academic research and scientific papers
Olivanic Acid Analogues. Part 11. Ozonolysis of α-Ethylideneazetidinones: Ozonide Fragmentation to α-Amino Acid-N-carboxyanhydrides
Bateson, John H.,Fell, Stephen C. M.,Kaura, Arun C.,Southgate, Robert
, p. 1577 - 1582 (2007/10/02)
Ozonolysis of (E)-7-ethylideneoctane-2-spirocyclohexan>-8-one failed to provide the α-oxoazetidinone 2, but afforded an α-amino acid-N-carboxyanhydride nonane-2-spirocyclohexane>-7,9-dione 5. octane-2-spirocyclohexane>-7,8-dione 2 was instead obtained from the trans-ketone 9 by a sequence involving Baeyer-Villiger oxidation of the azido ketone 10.
