1433955-95-3Relevant academic research and scientific papers
Enantioselective Conjugate Addition of 2-Acylimidazoles with Nitroalkenes Promoted by Chiral-at-Metal Rhodium(III) Complexes
Thota, Ganesh Kumar,Sun, Gui-Jun,Deng, Tao,Li, Yi,Kang, Qiang
, p. 1094 - 1098 (2018/01/22)
An enantioselective conjugate addition of 2-acylimidazoles with nitroalkenes catalyzed by chiral-at-metal rhodium(III) complex under mild reaction conditions was developed, affording versatile γ-nitro ketone skeletons in good yields with excellent enantioselectivities (up to >99% ee). (Figure presented.).
Enantioselective nickel-catalyzed michael additions of 2-acetylazaarenes to nitroalkenes
Simpson, Alain J.,Lam, Hon Wai
, p. 2586 - 2589 (2013/07/26)
2-Acetylazaarenes undergo catalytic enantioselective Michael additions to nitroalkenes in the presence of a chiral Ni(II)-bis(oxazoline) complex. The process is tolerant of a range of azines or azoles in the pronucleophilic component, resulting in Michael products in moderate to high enantioselectivities.
