143503-67-7Relevant articles and documents
Unique Stereocontrol in Europium (III)-Catalyzed Cyanosilylation of chiral α-Alkoxy and α-Amino Aldehydes
Gu, Jin-Hua,Okamoto, Mikako,Terada, Masahiro,Mikami, Koichi,Nakai, Takeshi
, p. 1169 - 1172 (2007/10/02)
The Eu(III)-catalyzed cyanosilylations of chiral α-alkoxy and α-amino aldehydes are shown to exhibit syn diastereofacial selection, the degree increasing with an increase in steric bulk of the alkyl chain in the aldehydes.The mechanism of this catalytic p