1435488-52-0Relevant articles and documents
Dynamic resolution of lithiated ortho-trifluoromethyl styrene oxide and the effect of chiral diamines on the barrier to enantiomerisation
Mansueto, Rosmara,Perna, Filippo Maria,Salomone, Antonio,Florio, Saverio,Capriati, Vito
supporting information, p. 4911 - 4913 (2013/06/27)
The first dynamic thermodynamic resolution of a racemic oxiranyllithium is described with selectivities of up to 82:18 from a selection of three types of chiral ligands (seven ligands in total). Both (-)-sparteine and its (+)-surrogate were surprisingly found to increase the enantiomerisation barrier. The Royal Society of Chemistry.