143566-69-2Relevant academic research and scientific papers
Pyrazolato-bridged Binuclear Palladium(II) Compounds: Synthesis and Crystal Structure
Jain, Vimal K.,Kannan, S.,Tiekink, Edward R. T.
, p. 2231 - 2234 (1992)
Pyrazolato-bridged binuclear palladium(II) complexes of the type have been prepared.They were characterized by elemental analysis, 1H and 31P NMR data and in the case of by single-crystal X-ray diffraction methods.The structure determination shows two Pd atoms bridged by two dmpz ligands which form asymmetric Pd-N bond distances, an observation that may be correlated with the different trans influences associated with the Cl and P atoms which complete the square-planar geometries about the Pd atoms: monoclinic, space group P21/c, a = 20.164(1), b =10.140(1), c = 16.129(3) Angstroem, β = 111.71(1) deg, and Z = 4.The structure was refined to final R = 0.027 for 2906 reflections with I 2.5 ?(I).
