Pyrazolato-bridged Binuclear Palladium(II) Compounds: Synthesis and Crystal Structure

DOI: 10.1039/DT9920002231

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2231 - 2234 (1992)

Update date:2022-08-04

Topics:

Authors:

Jain, Vimal K.

Kannan, S.

Tiekink, Edward R. T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9920002231

Pyrazolato-bridged binuclear palladium(II) complexes of the type have been prepared.They were characterized by elemental analysis, ¹H and ³¹P NMR data and in the case of by single-crystal X-ray diffraction methods.The structure determination shows two Pd atoms bridged by two dmpz ligands which form asymmetric Pd-N bond distances, an observation that may be correlated with the different trans influences associated with the Cl and P atoms which complete the square-planar geometries about the Pd atoms: monoclinic, space group P2₁/c, a = 20.164(1), b =10.140(1), c = 16.129(3) Angstroem, β = 111.71(1) deg, and Z = 4.The structure was refined to final R = 0.027 for 2906 reflections with I <*> 2.5 ?(I).

Full text of DOI:10.1039/DT9920002231

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Pd₂Cl₂(C₃HN₂(CH₃)2)2(P(CH₃)2(C₆H₅))2}

Cas No:143566-69-2

R&D Labs maybe for 143566-69-2

Taizhou Sunny Chemical Co.,Ltd

Contact:+86-523-86920899 +86-13951172783

Address:No.11 Xingyuang road, Gaoyong Chemical Industry Park, Gaogang Jiangsu China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Wuhan Benjamin Pharmaceutical Chemical Co.,Ltd

Contact:86-27-52341789

Address:Room 1518 B suite, optical valley time square, No 111 Guanshan Road, Hongshan District,Wuhan,Hubei Province,China.
Sdow

website:http://www.sdowchem.com

Contact:86-135-2193 7483

Address:8-106 taiyue building
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.

Relevant to this article

Co(salen) catalyzed oxidation of 2,4,6-trisubstituted anilines with tert-butylhydroperoxide

Doi:10.1016/S0040-4039(00)60100-4
(1992)
Anti-cancer potential of (1,2-dihydronaphtho[2,1-b]furan-2-yl)methanone derivatives

Doi:10.1016/j.bmcl.2020.127476
(2020)
Cis configured bis phosphine platinum(II) chalcogenolate complexes: Structures, NMR and computational studies

Doi:10.1016/j.jorganchem.2013.03.030
(2013)
Optimized chemical probes for REV-ERBα

Doi:10.1021/jm400458q
(2013)
Stereoselective synthesis of (2S,3S,4R,5S)-3,4-dihydroxy-2,5- dihydroxymethyl pyrrolidine from l-sorbose

Doi:10.1016/j.carres.2013.03.017
(2013)
L-tert-Leucine derived urea-ammonium salts: Efficient bifunctional phase transfer catalysts for highly diastereo- and enantioselective aza-Henry reaction of isatin-derived N-Boc ketimines with α-aryl nitromethanes

Doi:10.1016/j.tet.2019.04.015
(2019)

Article Doi