Pyrazolato-bridged Binuclear Palladium(II) Compounds: Synthesis and Crystal Structure

DOI: 10.1039/DT9920002231

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2231 - 2234 (1992)

Update date:2022-08-04

Topics:

Authors:

Jain, Vimal K.

Kannan, S.

Tiekink, Edward R. T.

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Article abstract of DOI:10.1039/DT9920002231

Pyrazolato-bridged binuclear palladium(II) complexes of the type have been prepared.They were characterized by elemental analysis, ¹H and ³¹P NMR data and in the case of by single-crystal X-ray diffraction methods.The structure determination shows two Pd atoms bridged by two dmpz ligands which form asymmetric Pd-N bond distances, an observation that may be correlated with the different trans influences associated with the Cl and P atoms which complete the square-planar geometries about the Pd atoms: monoclinic, space group P2₁/c, a = 20.164(1), b =10.140(1), c = 16.129(3) Angstroem, β = 111.71(1) deg, and Z = 4.The structure was refined to final R = 0.027 for 2906 reflections with I <*> 2.5 ?(I).

Full text of DOI:10.1039/DT9920002231

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