Pyrazolato-bridged Binuclear Palladium(II) Compounds: Synthesis and Crystal Structure

DOI: 10.1039/DT9920002231

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2231 - 2234 (1992)

Update date:2022-08-04

Topics:

Authors:

Jain, Vimal K.

Kannan, S.

Tiekink, Edward R. T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9920002231

Pyrazolato-bridged binuclear palladium(II) complexes of the type have been prepared.They were characterized by elemental analysis, ¹H and ³¹P NMR data and in the case of by single-crystal X-ray diffraction methods.The structure determination shows two Pd atoms bridged by two dmpz ligands which form asymmetric Pd-N bond distances, an observation that may be correlated with the different trans influences associated with the Cl and P atoms which complete the square-planar geometries about the Pd atoms: monoclinic, space group P2₁/c, a = 20.164(1), b =10.140(1), c = 16.129(3) Angstroem, β = 111.71(1) deg, and Z = 4.The structure was refined to final R = 0.027 for 2906 reflections with I <*> 2.5 ?(I).

Full text of DOI:10.1039/DT9920002231

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Pd₂Cl₂(C₃HN₂(CH₃)2)2(P(CH₃)2(C₆H₅))2}

Cas No:143566-69-2

R&D Labs maybe for 143566-69-2

Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Rugao Jinling Chemical Co., Ltd.(expird)

Contact:0086-513-68005586

Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Linyi Shengxin Pharmaceutical R&D Co., Ltd

Contact:+86-18653953873

Address:West First of Yufeng Road, Yishui County

Relevant to this article

Co(salen) catalyzed oxidation of 2,4,6-trisubstituted anilines with tert-butylhydroperoxide

Doi:10.1016/S0040-4039(00)60100-4
(1992)
Anti-cancer potential of (1,2-dihydronaphtho[2,1-b]furan-2-yl)methanone derivatives

Doi:10.1016/j.bmcl.2020.127476
(2020)
Cis configured bis phosphine platinum(II) chalcogenolate complexes: Structures, NMR and computational studies

Doi:10.1016/j.jorganchem.2013.03.030
(2013)
Optimized chemical probes for REV-ERBα

Doi:10.1021/jm400458q
(2013)
Stereoselective synthesis of (2S,3S,4R,5S)-3,4-dihydroxy-2,5- dihydroxymethyl pyrrolidine from l-sorbose

Doi:10.1016/j.carres.2013.03.017
(2013)
L-tert-Leucine derived urea-ammonium salts: Efficient bifunctional phase transfer catalysts for highly diastereo- and enantioselective aza-Henry reaction of isatin-derived N-Boc ketimines with α-aryl nitromethanes

Doi:10.1016/j.tet.2019.04.015
(2019)

Article Doi