1435909-76-4 Usage
Uses
Used in Catalysis:
Bis[2-(4,6-difluorophenyl)-4-(2,4,6-triMethylphenyl)pyridinato-C2,N](picolinato)iridiuM(III),PhFIrPic is utilized as a catalyst in various chemical reactions due to the catalytic activity often associated with iridium complexes. Its ability to facilitate reactions under mild conditions and its stability make it a preferred choice in the catalysis industry.
Used in Organic Synthesis:
In the field of organic synthesis, Bis[2-(4,6-difluorophenyl)-4-(2,4,6-triMethylphenyl)pyridinato-C2,N](picolinato)iridiuM(III),PhFIrPic serves as a key component in the synthesis of complex organic molecules. Its role in facilitating specific types of bond formations and transformations is invaluable for the production of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Materials Science:
Bis[2-(4,6-difluorophenyl)-4-(2,4,6-triMethylphenyl)pyridinato-C2,N](picolinato)iridiuM(III),PhFIrPic is also employed in materials science for the development of new materials with unique electronic, optical, or catalytic properties. Bis[2-(4,6-difluorophenyl)-4-(2,4,6-triMethylphenyl)pyridinato-C2,N](picolinato)iridiuM(III),PhFIrPic's stability and the ability to fine-tune its properties through ligand design make it suitable for creating advanced materials for various applications.
Used in Research and Development:
In academic and industrial research settings, Bis[2-(4,6-difluorophenyl)-4-(2,4,6-triMethylphenyl)pyridinato-C2,N](picolinato)iridiuM(III),PhFIrPic is used as a model compound to study the fundamental aspects of coordination chemistry, ligand design, and the mechanisms of catalytic reactions. Its use in research aids in the discovery of new chemical processes and the development of innovative materials.
Check Digit Verification of cas no
The CAS Registry Mumber 1435909-76-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,4,3,5,9,0 and 9 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1435909-76:
(9*1)+(8*4)+(7*3)+(6*5)+(5*9)+(4*0)+(3*9)+(2*7)+(1*6)=184
184 % 10 = 4
So 1435909-76-4 is a valid CAS Registry Number.
1435909-76-4Relevant academic research and scientific papers
Kozhevnikov, Valery N.,Zheng, Yonghao,Clough, Matthew,Al-Attar, Hameed A.,Griffiths, Gareth C.,Abdullah, Khalid,Raisys, Steponas,Jankus, Vygintas,Bryce, Martin R.,Monkman, Andrew P.
, p. 2352 - 2358 (2013)
This article reports the systematic functionalization of FIrpic (1) with solubilizing alkyl groups (complexes 2-4) or mesityl groups (complexes 5 and 6). Complex 5 is shown to offer significant advantages over FIrpic (1) in terms of performance of sky-blue polymer-based phosphorescent organic light-emitting diodes (PhOLEDs) with a solution-processed emitting layer (λ maxEL 477 nm for 5). Devices with 5 doped into poly(vinylcarbazole) (PVK):OXD-7 gave a maximum luminous efficiency of 19.1 cd A-1 at a brightness of 5455 cd m2 with EQE 8.7%. Optimized multilayer devices with additional TPBi and LiF layers gave 23.7 cd A -1 and EQE 10.4%. These data compare favorably with leading literature values for sky-blue polymer-based PhOLEDs. The enhanced performance of 5 is ascribed to three main reasons: (i) reduced concentration quenching of 5; (ii) the higher radiative yield of 5; and (iii) improved solubility of 5 in organic solvents. Complex 5 should find widespread use as a soluble blue phosphor for displays and lighting applications using solution processing techniques.
Blue-ray iridium complex and preparation method and application thereof
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Paragraph 0032; 0039; 0040; 0041; 0042, (2019/10/01)
The invention discloses a blue-ray iridium complex and a preparation method and application thereof. The blue-ray iridium complex is composed of a difluorophenyl pyridine derivative and 2-picolinic acid through complexing, wherein the difluorophenyl pyrid
