98-98-6Relevant articles and documents
Base-Catalyzed Autoxidation of Weak Carbon Acids Using Poly(ethylene glycols) as Phase-Transfer Catalysts
Neumann, Ronny,Sasson, Yoel
, p. 1282 - 1284 (1984)
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The biosynthesis of caerulomycins in Streptomyces caeruleus. Isolation of a new caerulomycin and incorporation of picolinic acid and glycerol into caerulomycin A
Vining,McInnes,McCulloch,Smith,Walter
, p. 191 - 194 (1988)
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Copper(II)-Catalyzed Selective Para Amination of Arylamine with Pyrazole by C?H Functionalization
Xu, Jun,Du, Kui,Shen, Jiabin,Shen, Chao,Chai, Kejie,Zhang, Pengfei
, p. 3675 - 3679 (2018)
A coordinating activation strategy for selective para amination of arylamine with pyrazole is developed. Various substrates are compatible, giving the corresponding products in moderate to good yields. This strategy provides a practical solution for the efficient synthesis of arylamine-containing pharmacophores from simple starting materials. A single electron transfer mechanism is suggested for this reaction.
ANODIC OXIDATION OF 2-PICOLINE
Toomey, Joseph E.,Chaney, Gregory A.
, p. 697 - 704 (1991)
Concentrations, temperature, and current density for anodic oxidation of 2-picoline were optimized by using three statistically designed experiments.Criteria for optimization were chemical yield, current efficiency, space-time yield and rate of anode corrosion.
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Helbing,Viscontini
, p. 2284,2288 (1976)
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Use of bacteria for rapid, pH-neutral, hydrolysis of the model hydrophobic carboxylic acid ester p-nitrophenyl picolinate
Forest, Alexandra E.,Goldstine, Gordon G.,Murray, Sean R.,Schrodi, Yann
, p. 435 - 439,5 (2012)
Caulobacter crescentus, Escherichia coli and Bacillus subtilis cultures promote the hydrolysis of the model ester p-nitrophenyl picolinate (PNPP) at neutral pH with high efficiency. Hydrolysis is related to cell concentration, while the interaction of PNPP with both bacterial cells and their extracellular molecules is required for a maximum rate of PNPP hydrolysis in C. crescentus cultures. Furthermore, C. crescentus cultures hydrolyse PNPP at concentrations useful in synthetic chemistry.
Reaction Acceleration Promoted by Partial Solvation at the Gas/Solution Interface
Qiu, Lingqi,Wei, Zhenwei,Nie, Honggang,Cooks, R. Graham
, p. 1362 - 1365 (2021/09/14)
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent polarity. Partial solvation at the gas/solution interface is a major contributor to the 104-fold reaction acceleration seen in bimolecular but not unimolecular reactions in microdroplets. Reaction acceleration can be used to manipulate selectivity by solvent choice.
{BW12O40} Hybrids Modified by in Situ Synthesized Rigid Ligand with Supercapacitance and Photocatalytic Properties
Du, Nana,Gong, Lige,Wang, Chunmei,Wang, Chunxiao,Yu, Kai,Zhang, Wenjia,Zhou, Baibin
supporting information, p. 16357 - 16369 (2021/11/13)
Organic rigid ligand-modified polyoxometalate-based materials possess complex and diverse structures, promising electrochemical energy storage properties and outstanding photocatalytic capabilities. Hence, two new [BW12O40]5-(abbreviated as {BW12O40})-based inorganic-organic hybrids [{Cu(en)2(H2O)}][{Cu(pdc)(en)}{Cu(en)2}(BW12O40)]·2H2O (1) and [{CuI5(pz)6(H2O)4}(BW12O40)] (2) (pdc = 2-picolinate, en = ethylenediamine, pz = pyrazine) were successfully synthesized through a hydrothermal method. Among them, pdc and pz were obtained by in situ transformation from 2,6-pyridinedicarboxylic acid (H2 pydc) and 2,3-pyrazinedicarboxylic acid (H2pzdc), respectively. In compound 1, the {BW12O40} clusters as an intermediate junction connect with {Cu(pdc)(en)}{Cu(en)2} and {Cu(en)2(H2O)} to form monomers, which in turn form supramolecular chains, sheets, and space network via hydrogen bonding. The {BW12O40} clusters are packed into copper-pyrazine frameworks in compound 2, and a unique polyoxometalate-based metal organic frameworks (POMOFs) structure with a new topology of {12}2{6.123.142}2{62.12.142.18}{62.123.16}{6}6 is formed via covalent bonds. When used as electrode materials for supercapacitors, the values of specific capacitance are 651.56 F g-1 for 1-GCE and 584.43 F g-1 for 2-GCE at a current density of 2.16 A g-1 and good cycling stability (90.94%, 94.81% of the initial capacity after 5000 cycles at 15.12 A g-1, respectively). The kinetic analysis reveals that surface capacitance plays a major role. Furthermore, both compounds can effectively degrade Rhodamine B (RhB) and Methylene blue (MB), showing the outstanding photocatalytic performance.
Method for preparing organic acid by oxidative cleavage of aromatic secondary alcohol
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Paragraph 0043-0046; 0051, (2020/09/16)
The invention relates to a method for preparing organic acids by oxidation of aromatic secondary alcohols. With air or oxygen as an oxygen source, a copper salt and an organic ligand as catalysts, aninorganic alkali is added, and aromatic secondary alcohols are subjected to carbon-carbon bond oxidative cracking to obtain the organic acids. The method has the advantages of high oxidation efficiency and high product yield; with the use of air or oxygen as the oxygen source, the method is economical and environmentally friendly and has good application prospects.