143658-46-2

Basic information

• Product Name: methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate
• Synonyms: methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate
• CAS NO: 143658-46-2
• Molecular Weight: 294.391
• Mol File: 143658-46-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate(143658-46-2)
• EPA Substance Registry System: methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate(143658-46-2)

Safety Data

• Hazardous Substances Data: 143658-46-2(Hazardous Substances Data)

Upstream product

• 143658-43-9 ethyl <2,6,6-trimethyl-2-cyclohexenyl>acetate 
• 143658-44-0 2-<(S)-2,6,6-trimethyl-2-cyclohexenyl>ethanol 
• 134780-16-8 (R)-2,4,4-trimethyl-2-cyclohexen-1-ol 
• 143658-45-1 2-(2,6,6-trimethyl-2-cyclohexenyl)ethanal 
• 1104-78-5 dimethyl 2-(triphenylphosphoranylidene)succinate 

Downstream Products

• 143658-47-3 3-hydroxymethyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-penten-1-ol 
• 143728-94-3 3-formyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal 

Relevant articles and documents

Synthesis of Mono- and Sesqui-terpenoids. XXI. Synthesis and Absolute Configuration of (E)-3-Formyl-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal, a Sesquiterpenoid from a Marine Alga, Caulerpa ashmeadii

A six-step synthesis of the enantiomers of (E)-3-formyl-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal has been achieved, starting from the enantiomers of 2,4,4-trimethyl-2-cyclohexenol.By comparing the sign of the optical rotation of the naturally occurring