14367-05-6Relevant articles and documents
Reductive aldol-type reaction of α,β-unsaturated esters with aldehydes or ketones in the presence of Rh catalyst and Et2Zn
Sato, Kazuyuki,Isoda, Motoyuki,Tokura, Yoriko,Omura, Keiko,Tarui, Atsushi,Omote, Masaaki,Kumadaki, Itsumaro,Ando, Akira
, p. 5913 - 5915 (2013/10/21)
The reaction of RhCl(PPh3)3 with Et2Zn easily generated a rhodium-hydride complex (Rh-H) that added to α,β-unsaturated esters to form rhodium enolate complexes by formal 1,4-reduction. These rhodium enolates gave the corre
Chromium(II)-Mediated Reformatsky Reactions of Carboxylic Esters with Aldehydes
Wessjohann, Ludger,Gabriel, Tobias
, p. 3772 - 3774 (2007/10/03)
-
Design of α-Alkyl β-Hydroxy Esters Suitable for Providing Optical Resolution by Lipase Hydrolysis
Itoh, Toshiyuki,Kuroda, Keiko,Tomosada, Miki,Takagi, Yumiko
, p. 797 - 804 (2007/10/02)
A study of the lipase-catalyzed hydrolyses of various α-substituted β-acetoxy esters revealed that a sulfur functional group in the ester, which could play an important role in the stereorecognition by lipase A6 (Aspergillus sp.) and an anti conformation