143738-99-2Relevant academic research and scientific papers
Diastereoselective addition of metal-coordinated and 'naked' nucleophilic reagents to norephedrine derived 2-acyl-N-tosyl-oxazolidines
Poli, Giovanni,Maccagni, Elisa,Manzoni, Leonardo,Pilati, Tullio,Scolastico, Carlo
, p. 1759 - 1776 (1997)
The addition of tri-s-butyl borohydrides to the 2-acetyl-1,3-oxazolidine 1 could be directed with high selectivity to either the Si or the Re π-carbonyl face under chelating or non-coordinating conditions respectively. Addition of hydrides to the correspo
Asymmetric synthesis with diphenylphosphine oxides: Bicyclic aminals and oxazolidines as chiral auxiliaries
O'Brien, Peter,Warren, Stuart
, p. 3431 - 3444 (2007/10/03)
Syntheses of six novel phosphine oxide chiral auxiliaries are described. The auxiliaries are composed of the diphenylphosphinoyl (Ph2PO) group and either proline-derived bicyclic aminals or norephedrine-derived oxazolidines. One auxiliary is us
Diastereoselective Addition of Metal-coordinated and 'Naked' Tri-sec-butylborohydrides to a Norephedrine-derived 2-Acetyloxazolidine
Manzoni, Leonardo,Pilati, Tullio,Poli, Giovanni,Scolastico, Carlo
, p. 1027 - 1029 (2007/10/02)
The addition of tri-sec-butylborohydrides to the 2-acetyl-1,3-oxazolidine 1 can be directed with high selectivity to either the Si or the Re ?-carbonyl face under chelating or non-coordinating conditions, respectively.
